SET PASSWORD [FORuser] = { PASSWORD('some password') | OLD_PASSWORD('some password') | 'encrypted password' }
        The SET PASSWORD statement
        assigns a password to an existing MySQL user account.
      
        If the password is specified using the
        PASSWORD() or
        OLD_PASSWORD() function, the
        literal text of the password should be given. If the password is
        specified without using either function, the password should be
        the already-encrypted password value as returned by
        PASSWORD().
      
        With no FOR clause, this statement sets the
        password for the current user. Any client that has connected to
        the server using a nonanonymous account can change the password
        for that account.
      
        With a FOR clause, this statement sets the
        password for a specific account on the current server host. Only
        clients that have the UPDATE
        privilege for the mysql database can do this.
        The user value should be given in
        user_name@host_nameuser_name and
        host_name are exactly as they are
        listed in the User and
        Host columns of the
        mysql.user table entry. For example, if you
        had an entry with User and
        Host column values of
        'bob' and '%.loc.gov', you
        would write the statement like this:
      
SET PASSWORD FOR 'bob'@'%.loc.gov' = PASSWORD('newpass');
That is equivalent to the following statements:
UPDATE mysql.user SET Password=PASSWORD('newpass')
  WHERE User='bob' AND Host='%.loc.gov';
FLUSH PRIVILEGES;
          If you are connecting to a MySQL 4.1 or later server using a
          pre-4.1 client program, do not use the preceding
          SET PASSWORD or
          UPDATE statement without
          reading Section 5.5.6.3, “Password Hashing in MySQL”, first. The
          password format changed in MySQL 4.1, and under certain
          circumstances it is possible that if you change your password,
          you might not be able to connect to the server afterward.
        
        You can see which account the server authenticated you as by
        executing SELECT CURRENT_USER().
      
MySQL Enterprise. For automated notification of users without passwords, subscribe to the MySQL Enterprise Monitor. For more information, see http://www.mysql.com/products/enterprise/advisors.html.


User Comments
Another equivalent command (as SUPER) is:
GRANT USAGE ON *.* TO user@host IDENTIFIED BY 'password';
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